[doc] Clarify exception in `multiprocessing.cpu_count` (GH-23660)

Previous wording didn't explain the slightly unintuitive behavior.

Co-authored-by: kj <28750310+Fidget-Spinner@users.noreply.github.com>

Doc/library/multiprocessing.rst

diff --git a/Doc/library/multiprocessing.rst b/Doc/library/multiprocessing.rst
index c9b2a37..41cd40a 100644
--- a/Doc/library/multiprocessing.rst
+++ b/Doc/library/multiprocessing.rst
@@ -951,7 +951,8 @@
    use.  The number of usable CPUs can be obtained with
    ``len(os.sched_getaffinity(0))``
 
-   May raise :exc:`NotImplementedError`.
+   When the number of CPUs cannot be determined a :exc:`NotImplementedError`
+   is raised.
 
    .. seealso::
       :func:`os.cpu_count`